Proton transfer reactions of hydrazine-boranes
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چکیده
منابع مشابه
Kinetics of proton-coupled electron-transfer reactions
The kinetics of proton-coupled electron-transfer (pcet) reactions are reported for Mn4O4(O2PPh2)6, 1, and [Mn4O4(O2PPh2)6] , 1 , with phenothiazine (pzH). Both pcet reactions form 1H, by H transfer to 1 and by hydride transfer to 1 . Surprisingly, the rate constants differ by only 25% despite large differences in the formal charges and driving force. The driving force is proportional to the dif...
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ژورنال
عنوان ژورنال: Journal of Physical Organic Chemistry
سال: 2015
ISSN: 0894-3230
DOI: 10.1002/poc.3401